MATERIAL SAFETY DATA SHEETMATERIAL SAFETY DATA SHEET
PRODUCT NAME: MAP GAS OIL, FULL RANGE
MARATHON MSDS NO: 0186MAR020
PRODUCT NAME: MANUFACTURER / DISTRIBUTOR:
MAP GAS OIL, FULL RANGE MARATHON ASHLAND PETROLEUM LLC
539 SOUTH MAIN STREET
SYNONYMS: FINDLAY OH 45840
FULL RANGE GAS OIL; GAS OIL (PETROLEUM)
HEAVY ATMOSPHERIC; GAS OIL FULL RANGE; EMERGENCY PHONE NUMBERS:
HEAVY ATMOSPHERIC GAS OIL; MAP GAS OIL, (877)627-5463
FULL RANGE (800)424-9300
CHEM FAMILY: PETROLEUM GAS OIL MSDS INFORMATION: (419)421-3070
CHEM FORMULA: MIXTURE
PRODUCT CODE: NONE MSDS REVISION DATE: 12/23/1999
INFORMATION SUPPLIED BY: CRAIG M. PARKER
MANAGER, TOXICOLOGY AND PRODUCT SAFETY
MAP GAS OIL, FULL RANGE (CAS # 68783-08-4) IS A/AN
COMPLEX MIXTURE OF PARAFFINIC, CYCLOPARAFFINIC, OLEFINIC AND AROMATIC
HYDROCARBONS (PREDOMINANTLY C7 THROUGH C35) OBTAINED BY THE
DISTILLATION OF CRUDE OIL.
PERCENT RANGE CAS NUMBER
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GAS OIL, FULL RANGE 100.00 68783-08-4
LIMIT TYPE SOURCE
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MAP GAS OIL, FULL RANGE NONE ESTABLISHED
GAS OIL, FULL RANGE NONE ESTABLISHED
MAP FULL RANGE GAS OIL IS A LIGHT TO DARK BROWN COLORED LIQUID. IT IS
CONSIDERED TO BE A COMBUSTIBLE LIQUID PER THE OSHA HAZARD COMMUNICATION
STANDARD AND SHOULD BE KEPT AWAY FROM HEAT, FLAME AND SOURCES OF IGNITION.
NEVER SIPHON THIS PRODUCT BY MOUTH. IF SWALLOWED, GAS OIL MAY GET SUCKED
INTO THE LUNGS (ASPIRATED) AND CAUSE LUNG DAMAGE OR EVEN DEATH. LONG TERM
SKIN EXPOSURE TO GAS OILS HAS CAUSED CANCER IN LABORATORY ANIMALS.
REPEATED SKIN CONTACT HAS PRODUCED SYSTEMIC TOXICITY IN LABORATORY ANIMALS.
OSHA WARNING LABEL:
DANGER!
COMBUSTIBLE LIQUID.
ASPIRATION (INADVERTENT SUCTION) OF LIQUID INTO THE LUNGS
CAN PRODUCE CHEMICAL PNEUMONIA OR EVEN DEATH.
LONG-TERM SKIN EXPOSURE TO GAS OILS HAS CAUSED
CANCER IN LABORATORY ANIMALS.
REPEATED SKIN CONTACT HAS PRODUCED
SYSTEMIC TOXICITY IN LABORATORY ANIMALS.
LIQUID CONTACT MAY RESULT IN SLIGHT EYE IRRITATION.
PROLONGED OR REPEATED LIQUID CONTACT CAN CAUSE DEFATTING AND DRYING OF THE SKIN WHICH MAY PRODUCE SEVERE IRRITATION OR DERMATITIS.
HIGH VAPOR CONCENTRATIONS MAY PRODUCE HEADACHE, GIDDINESS, VERTIGO, AND ANESTHETIC STUPOR.
INGESTION MAY RESULT IN NAUSEA, VOMITING, DIARRHEA AND RESTLESSNESS. ASPIRATION (INADVERTENT SUCTION) OF LIQUID INTO THE LUNGS MUST BE AVOIDED AS EVEN SMALL QUANTITIES IN THE LUNGS CAN PRODUCE CHEMICAL PNEUMONITIS, PULMONARY EDEMA/HEMORRHAGE AND EVEN DEATH.
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS DETERMINED THAT THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF UNTREATED VACUUM DISTILLATES, ACID-TREATED OILS, AND AROMATIC OILS, INCLUDING EXTRACTS FROM SOLVENT TREATMENT OF DISTILLATES AND THE HIGH BOILING FRACTION OF CATALYTICALLY CRACKED OILS IN ANIMALS.
PREEXISTING SKIN CONDITIONS AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO COMPONENTS OF GAS OIL AND/OR HEAVY MIDDLE DISTILLATE.
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IF SYMPTOMS OR IRRITATION OCCUR, CALL A PHYSICIAN.
WASH WITH SOAP AND LARGE AMOUNTS OF WATER. REMOVE CONTAMINATED CLOTHING. IF SYMPTOMS OR IRRITATION OCCUR, CALL A PHYSICIAN.
IF AFFECTED, MOVE PERSON TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF NOT BREATHING OR NO HEARTBEAT, GIVE ARTIFICIAL RESPIRATION OR CARDIOPULMONARY RESUSCITATION (CPR). IMMEDIATELY CALL A PHYSICIAN. IF SYMPTOMS OR IRRITATION OCCUR WITH ANY EXPOSURE, CALL A PHYSICIAN.
INGESTION NOT LIKELY. IF SWALLOWED, DO NOT INDUCE VOMITING AND DO NOT GIVE LIQUIDS. IMMEDIATELY CALL A PHYSICIAN.
NO DATA AVAILABLE.
FLASH POINT: >100 F
AUTOIGNITION TEMP: NO DATA AVAILABLE
EXPLOSIVE LIMITS (% BY VOLUME IN AIR)
LOWER: NO DATA AVAILABLE
UPPER: NO DATA AVAILABLE
THIS PRODUCT HAS BEEN DETERMINED TO BE A COMBUSTIBLE LIQUID PER THE OSHA HAZARD COMMUNICATION STANDARD AND SHOULD BE HANDLED ACCORDINGLY. FOR ADDITIONAL FIRE RELATED INFORMATION, SEE NFPA 30 OR THE NORTH AMERICAN EMERGENCY RESPONSE GUIDE 128.
FOR SMALL FIRES, CLASS B FIRE EXTINGUISHING MEDIA SUCH AS CO2, DRY CHEMICAL, FOAM (AFFF/ATC) OR WATER SPRAY CAN BE USED. FOR LARGE FIRES, WATER SPRAY, FOG OR FOAM (AFFF/ATC) CAN BE USED. FIRE FIGHTING SHOULD BE ATTEMPTED ONLY BY THOSE WHO ARE ADEQUATELY TRAINED AND EQUIPPED WITH PROPER PROTECTIVE EQUIPMENT.
AVOID USE OF STRAIGHT WATER STREAMS. WATER SPRAY AND FOAM (AFFF/ATC) MUST BE APPLIED CAREFULLY TO AVOID FROTHOVER. AVOID EXCESSIVE APPLICATION. USE WATER SPRAY TO COOL EXPOSED SURFACES FROM AS FAR A DISTANCE AS POSSIBLE. KEEP RUN-OFF WATER OUT OF SEWERS AND WATER SOURCES.
ISOLATE AND EVACUATE AREA. SHUT OFF SOURCE IF SAFE TO DO SO. ADVISE NATIONAL RESPONSE CENTER (800-424-8802) IF SUBSTANCE HAS ENTERED A WATERWAY. NOTIFY LOCAL HEALTH AND POLLUTION CONTROL AGENCIES, IF APPROPRIATE. CONTAIN LIQUID WITH SAND OR SOIL. RECOVER AND RETURN FREE LIQUID TO PROPER CONTAINERS. USE SUITABLE ABSORBENT MATERIALS SUCH AS VERMICULITE, SAND, OR CLAY TO CLEAN UP RESIDUAL LIQUIDS.
COMPLY WITH ALL APPLICABLE OSHA, NFPA AND CONSISTENT LOCAL REQUIREMENTS. USE APPROPRIATE GROUNDING AND BONDING PRACTICES. STORE IN PROPERLY CLOSED CONTAINERS THAT ARE APPROPRIATELY LABELED. DO NOT EXPOSE TO HEAT, OPEN FLAME, OXIDIZERS OR OTHER SOURCES OF IGNITION. DO NOT CUT, GRIND OR WELD ON EMPTY CONTAINERS SINCE THEY MAY CONTAIN EXPLOSIVE RESIDUES. AVOID SKIN CONTACT. EXERCISE GOOD PERSONAL HYGIENE INCLUDING REMOVAL OF SOILED CLOTHING AND PROMPT WASHING WITH SOAP AND WATER.
LOCAL OR GENERAL EXHAUST REQUIRED WHEN USING AT ELEVATED TEMPERATURES THAT GENERATE VAPORS OR MISTS.
USE APPROVED ORGANIC VAPOR CHEMICAL CARTRIDGE OR SUPPLIED AIR RESPIRATORS WHEN MATERIAL PRODUCES VAPORS THAT EXCEED PERMISSIBLE LIMITS OR EXCESSIVE VAPORS ARE GENERATED. OBSERVE RESPIRATOR PROTECTION FACTOR CRITERIA CITED IN ANSI Z88.2. SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED FOR FIRE FIGHTING.
IMPERMEABLE GLOVES (E.G., NITRILE, VITON, TYVEK/SARANEX 23) TO PREVENT SKIN CONTACT.
USE GOGGLES AND FACESHIELD WHEN HANDLING HOT MATERIAL.
USE MECHANICAL VENTILATION EQUIPMENT THAT IS EXPLOSION-PROOF. USE CHEMICAL RESISTANT APRON OR OTHER PROTECTIVE CLOTHING TO AVOID SKIN CONTACT.
BOILING POINT: 250-950 F MELTING POINT: NO DATA AVAILABLE SPECIFIC GRAVITY (H20=1): 0.80-0.93 PACKING DENSITY (KG/M3): NO DATA AVAILABLE % SOLUBILITY IN WATER: NEGLIGIBLE VAPOR DENSITY (AIR=1): NO DATA AVAILABLE VAPOR PRESSURE: <1 MM HG @ 100 F PH INFORMATION: NO DATA AVAILABLE % VOLATILES BY VOL: NO DATA AVAILABLE EVAPORATION RATE: NO DATA AVAILABLE APPEARANCE: LIGHT TO DARK BROWN LIQUID ODOR: HYDROCARBON ODOR THRESHOLD (PPM): NO DATA AVAILABLE
DENSITY: 6.6-7.8 LBS/GALLON
THE MATERIAL IS STABLE AT 70 F, 760MM PRESSURE.
EXCESSIVE HEAT, SOURCES OF IGNITION.
CARBON MONOXIDE, ALDEHYDES, AROMATICS, OTHER HYDROCARBONS.
STRONG OXIDIZING AGENTS SUCH AS CHLORATES, NITRATES, PEROXIDES.
WILL NOT OCCUR.
NO DATA AVAILABLE.
NO DATA AVAILABLE.
LIFETIME SKIN PAINTING STUDIES IN ANIMALS WITH GAS OIL AND/OR ITS MAJOR COMPONENTS HAVE PRODUCED TUMORS FOLLOWING PROLONGED AND REPEATED SKIN CONTACT. REPEATED DERMAL APPLICATION HAS PRODUCED SEVERE IRRITATION AND SYSTEMIC TOXICITY IN SUBACUTE TOXICITY STUDIES. SOME COMPONENTS OF GAS OILS, I.E., PARAFFINS AND OLEFINS, HAVE BEEN SHOWN TO PRODUCE A SPECIES SPECIFIC, SEX HORMONAL DEPENDENT KIDNEY LESION IN MALE RATS FROM REPEATED ORAL OR INHALATION EXPOSURE. SUBSEQUENT RESEARCH HAS SHOWN THAT THE KIDNEY DAMAGE DEVELOPS VIA THE FORMATION OF ALPHA-2U-GLOBULIN, A MECHANISM UNIQUE TO THE MALE RAT. HUMANS DO NOT FORM ALPHA-2U-GLOBULIN, THEREFORE, THE KIDNEY EFFECTS RESULTING FROM THIS MECHANISM ARE NOT RELEVANT IN HUMANS. SOME COMPONENTS OF GAS OILS WERE FOUND TO BE POSITIVE IN A FEW MUTAGENICITY TESTS WHILE NEGATIVE IN THE MAJORITY OF OTHERS. THE EXACT RELATIONSHIP BETWEEN THESE RESULTS AND HUMAN HEALTH IS NOT KNOWN.
NO DATA AVAILABLE.
THIS PRODUCT AS PRODUCED IS NOT SPECIFICALLY LISTED AS AN EPA RCRA HAZARDOUS WASTE ACCORDING TO FEDERAL REGULATIONS (40 CFR 260-271). HOWEVER, WHEN DISCARDED, SPILLED OR DISPOSED OF, IT MAY MEET THE CRITERIA OF AN "IGNITABLE" HAZARDOUS WASTE. THIS MATERIAL COULD ALSO BECOME A HAZARDOUS WASTE IF MIXED OR CONTAMINATED WITH A LISTED HAZARDOUS WASTE. IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF DISPOSAL MATERIAL IS HAZARDOUS ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS.
49 CFR 172.101:
PROPER SHIPPING NAME: GAS OIL
DOT CLASSIFICATION: 3
DOT IDENTIFICATION NUMBER: UN 1202
PACKING GROUP: PG III
THE FOLLOWING REGULATIONS APPLY TO THIS PRODUCT:
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200):
THIS PRODUCT HAS BEEN EVALUATED AND DETERMINED TO BE HAZARDOUS AS
DEFINED IN OSHA'S HAZARD COMMUNICATION STANDARD.
EPA TOXIC SUBSTANCES CONTROL ACT (40 CFR PART 710):
THIS PRODUCT AND/OR ITS COMPONENTS ARE LISTED ON THE TSCA CHEMICAL
INVENTORY.
EPA SARA TITLE III SUPERFUND AMENDMENTS & REAUTHORIZATION ACT - EMERGENCY
PLANNING & COMMUNITY RIGHT-TO-KNOW ACT OF 1986.
EXTREMELY HAZARDOUS SUBSTANCES (40 CFR PART 355):
THIS PRODUCT CONTAINS THE FOLLOWING COMPONENT(S) IDENTIFIED ON APPENDIX
A AND B OF THE EXTREMELY HAZARDOUS SUBSTANCE LIST (AT A LEVEL OF 1% OR
GREATER IF HAZARDOUS; 0.1% OR GREATER IF CARCINOGENIC): NONE.
EMERGENCY RELEASE NOTIFICATIONS (40 CFR PART 355):
THIS PRODUCT CONTAINS THE FOLLOWING COMPONENT(S) IDENTIFIED EITHER AS AN
EXTREMELY HAZARDOUS SUBSTANCE (40 CFR 355) OR A CERCLA HAZARDOUS
SUBSTANCE (40 CFR 302) WHICH IN CASE OF A SPILL OR RELEASE MAY BE
SUBJECT TO EMERGENCY RELEASE REPORTING REQUIREMENTS: NONE.
MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR PART 370):
THE FOLLOWING EPA HAZARD CATEGORIES APPLY TO THIS PRODUCT:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
FIRE HAZARD
MSDS'S OR A LIST OF MSDS'S AND THEIR HAZARDS (SEE EPA HAZARD CATEGORIES
ABOVE) MAY BE REQUIRED TO BE SUBMITTED TO THE STATE EMERGENCY RESPONSE
COMMISSION (SERC), LOCAL EMERGENCY PLANNING COMMITTEE (LEPC) AND LOCAL
FIRE DEPARTMENT (LFD).
IN ADDITION, A TIER II OR TIER I FORM MAY BE REQUIRED TO BE SUBMITTED
ANNUALLY TO THE SERC, LEPC AND LFD IF APPLICABLE THRESHOLD REPORTING
QUANTITIES ARE EXCEEDED. CURRENT FEDERAL THRESHOLDS ARE:
10,000 POUNDS OR MORE OF AN OSHA HAZARDOUS SUBSTANCE
OR
500 POUNDS OR THE THRESHOLD PLANNING QUANTITY WHICHEVER IS LESS,
OF AN EXTREMELY HAZARDOUS SUBSTANCE.
NOTE: THRESHOLDS MAY VARY ACCORDING TO LOCAL AND STATE REGULATIONS.
TOXIC CHEMICAL RELEASE REPORTING (40 CFR PART 372):
THIS PRODUCT CONTAINS THE FOLLOWING COMPONENT(S) (AT A LEVEL OF 1% OR
GREATER IF HAZARDOUS; 0.1% OR GREATER IF CARCINOGENIC) THAT MAY BE
SUBJECT TO REPORTING ON THE TOXIC RELEASE INVENTORY (TRI) FORM R: NONE.
NFPA CLASSIFICATION HMIS CLASSIFICATION HAZARD RATING
HEALTH: 2 HEALTH: 2 0 - LEAST
FIRE: 2 FIRE: 2 1 - SLIGHT
REACTIVITY: 1 REACTIVITY: 1 2 - MODERATE
OTHER: - PERSONAL PROTECTION: * 3 - HIGH
4 - EXTREME
* SEE SECTION 8 FOR GUIDANCE IN SELECTION OF PERSONAL PROTECTIVE
EQUIPMENT.
Updated: