MATERIAL SAFETY DATA SHEETMATERIAL SAFETY DATA SHEET
PRODUCT NAME: MAPLLC PETROLEUM CRUDE OIL
MARATHON MSDS NO: 0110MAR019
PRODUCT NAME: MANUFACTURER / DISTRIBUTOR:
MAPLLC PETROLEUM CRUDE OIL MARATHON ASHLAND PETROLEUM LLC
539 SOUTH MAIN STREET
SYNONYMS: FINDLAY OH 45840
CRUDE OIL, MAPLLC; MAPLLC CRUDE OIL;
MAPLLC PETROLEUM CRUDE OIL; PETROLEUM EMERGENCY PHONE NUMBERS:
CRUDE OIL, MAPLLC (877)627-5463
(800)424-9300
CHEM FAMILY: PETROLEUM HYDROCARBON MSDS INFORMATION: (419)421-3070
CHEM FORMULA: COMPLEX MIXTURE
PRODUCT CODE: NONE MSDS REVISION DATE: 06/11/1998
INFORMATION SUPPLIED BY: CRAIG M. PARKER
MANAGER, TOXICOLOGY AND PRODUCT SAFETY
MAPLLC PETROLEUM CRUDE OIL (CAS # 8002-05-9) IS A/AN
COMPLEX MIXTURE OF PARAFFINS, CYCLOPARAFFINS AND AROMATIC
HYDROCARBONS. CAN CONTAIN MINOR AMOUNTS OF SULFUR, NITROGEN, AND
OXYGEN COMPOUNDS AS WELL AS TRACE AMOUNTS OF HEAVY METALS SUCH AS
NICKEL, VANADIUM AND LEAD. COMPOSITION VARIES DEPENDING ON SOURCE OF
CRUDE.
PERCENT RANGE CAS NUMBER
------------- ---------------
PETROLEUM CRUDE OIL 98.00-100.00 8002-05-9 TOLUENE 0.00- 5.00 108-88-3 XYLENE 0.00- 5.00 1330-20-7 HYDROGEN SULFIDE 0.00- 4.00 7783-06-4 SULFUR COMPOUNDS 0.00- 3.00 MIXTURE NORMAL HEXANE 0.00- 3.00 110-54-3 BENZENE 0.00- 2.00 71-43-2
LIMIT TYPE SOURCE
------------------- --------- ----------
MAPLLC PETROLEUM CRUDE OIL NONE ESTABLISHED
PETROLEUM CRUDE OIL NONE ESTABLISHED
TOLUENE 50.00 PPM 8 HR TWA ACGIH
100.00 PPM 8 HR TWA OSHA*
150.00 PPM STEL OSHA*
* THE MANUFACTURER HAS VOLUNTARILY ELECTED
TO REFLECT EXPOSURE LIMITS CONTAINED IN
OSHA'S 1989 AIR CONTAMINANTS STANDARD IN ITS
MSDS'S, EVEN THOUGH CERTAIN OF THOSE EXPOSURE
LIMITS WERE VACATED IN 1992.
XYLENE 100.00 PPM 8 HR TWA ACGIH
150.00 PPM STEL ACGIH
100.00 PPM 8 HR TWA OSHA*
150.00 PPM STEL OSHA*
* THE MANUFACTURER HAS VOLUNTARILY ELECTED
TO REFLECT EXPOSURE LIMITS CONTAINED IN
OSHA'S 1989 AIR CONTAMINANTS STANDARD IN ITS
MSDS'S, EVEN THOUGH CERTAIN OF THOSE EXPOSURE
LIMITS WERE VACATED IN 1992.
HYDROGEN SULFIDE 10.00 PPM 8 HR TWA ACGIH
15.00 PPM STEL ACGIH
10.00 PPM 8 HR TWA OSHA*
15.00 PPM STEL OSHA*
* THE MANUFACTURER HAS VOLUNTARILY ELECTED
TO REFLECT EXPOSURE LIMITS CONTAINED IN
OSHA'S 1989 AIR CONTAMINANTS STANDARD IN ITS
MSDS'S, EVEN THOUGH CERTAIN OF THOSE EXPOSURE
LIMITS WERE VACATED IN 1992.
SULFUR COMPOUNDS NONE ESTABLISHED
NORMAL HEXANE 50.00 PPM 8 HR TWA ACGIH
500.00 PPM 8 HR TWA OSHA
BENZENE .50 PPM 8 HR TWA ACGIH
2.50 PPM STEL ACGIH
1.00 PPM 8 HR TWA OSHA
5.00 PPM STEL OSHA
OSHA ACTION LEVEL 0.50 PPM (8 HR TWA)
PETROLEUM CRUDE OIL IS AMBER TO BLACK IN COLOR DEPENDING ON THE SOURCE.
SOUR CRUDE POSSESSES A ROTTEN EGG OR SULFUR ODOR. CRUDE OIL IS A VOLATILE
AND EXTREMELY FLAMMABLE LIQUID AND VAPORS MAY CAUSE FLASH FIRES. KEEP AWAY
FROM HEAT, FLAME AND SOURCES OF IGNITION. CRUDE OIL CAN CONTAIN TOXIC
LEVELS OF HYDROGEN SULFIDE VAPORS THAT ACCUMULATE IN THE VAPOR SPACES OF
STORAGE AND TRANSPORT COMPARTMENTS. THESE VAPORS CAUSE EYE, SKIN, AND
RESPIRATORY TRACT IRRITATION AND ASPHYXIATION. CRUDE OIL CAN ALSO CONTAIN
SIGNIFICANT CONCENTRATIONS OF BENZENE WHICH HAS BEEN SHOWN TO CAUSE CANCER
OR BE TOXIC TO BLOOD-FORMING ORGANS. IF SWALLOWED, THE VOLATILE COMPONENTS
OF CRUDE OIL MAY GET SUCKED INTO THE LUNGS (ASPIRATED) AND CAUSE LUNG
DAMAGE OR EVEN DEATH.
OSHA WARNING LABEL:
DANGER!
FLAMMABLE LIQUID
MAY VENT HARMFUL CONCENTRATIONS OF HYDROGEN SULFIDE (H2S) GAS
WHICH CAN CAUSE RESPIRATORY IRRITATION AND ASPHYXIATION.
CONTAINS BENZENE WHICH MAY CAUSE
CANCER OR BE TOXIC TO BLOOD-FORMING ORGANS.
ASPIRATION (INADVERTENT SUCTION) OF LIQUID INTO THE LUNGS
CAN PRODUCE CHEMICAL PNEUMONIA OR EVEN DEATH.
LIQUID OR VAPOR CONTACT MAY RESULT IN SLIGHT EYE IRRITATION.
PROLONGED AND REPEATED LIQUID CONTACT CAN CAUSE DERMATITIS, FOLLICULITIS OR OIL ACNE.
VAPORS AND FUMES CAN CAUSE RESPIRATORY AND NASAL IRRITATION. SEE SECTIONS 7 AND 11 REGARDING THE TOXICITY AND POSSIBLE FORMATION/ACCUMULATION OF HYDROGEN SULFIDE GAS.
MAY BE TOXIC BY INGESTION. ASPIRATION (INADVERTENT SUCTION) OF LIQUID OF THE LIGHT HYDROCARBON FRACTION INTO THE LUNG CAN PRODUCE CHEMICAL PNEUMONITIS, PULMONARY EDEMA/HEMORRHAGE AND EVEN DEATH.
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS DETERMINED THAT THERE IS SUFFICIENT EVIDENCE FOR THE CARCINOGENICITY OF CRUDE OIL IN HUMANS. LIFETIME SKIN PAINTING STUDIES WITH DIFFERENT WHOLE CRUDE OILS HAVE PRODUCED TUMORS IN ANIMALS FOLLOWING PROLONGED AND REPEATED SKIN CONTACT. IARC HAS DETERMINED THAT THERE IS LIMITED EVIDENCE FOR THE CARCINOGENICITY OF CRUDE OIL IN ANIMALS.
PREEXISTING SKIN, EYE AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO COMPONENTS OF THIS PRODUCT.
FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. IF SYMPTOMS OR IRRITATION OCCUR, CALL A PHYSICIAN.
WASH WITH SOAP AND LARGE AMOUNTS OF WATER. REMOVE CONTAMINATED CLOTHING. IF SYMPTOMS OF IRRITATION OCCUR, CALL A PHYSICIAN.
IF AFFECTED, MOVE PERSON TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF NOT BREATHING OR IF NO HEARTBEAT, GIVE ARTIFICIAL RESPIRATION OR CARDIOPULMONARY RESUSCITATION (CPR). IMMEDIATELY CALL A PHYSICIAN. IF SYMPTOMS OF IRRITATION OCCUR WITH ANY EXPOSURE, CALL A PHYSICIAN.
INGESTION NOT LIKELY. IF SWALLOWED, DO NOT INDUCE VOMITING AND DO NOT GIVE LIQUIDS. IMMEDIATELY CALL A PHYSICIAN.
NO DATA AVAILABLE.
FLASH POINT: 20-100 F
AUTOIGNITION TEMP: NO DATA AVAILABLE
EXPLOSIVE LIMITS (% BY VOLUME IN AIR)
LOWER: NO DATA AVAILABLE
UPPER: NO DATA AVAILABLE
THIS MATERIAL HAS BEEN DETERMINED TO BE A FLAMMABLE LIQUID. VAPORS MAY TRAVEL ALONG THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY MANY SOURCES SUCH AS PILOT LIGHTS, SPARKS, ELECTRIC MOTORS, STATIC DISCHARGE, OR OTHER IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL HANDLING. FLASHBACK MAY OCCUR ALONG VAPOR TRAIL. FOR ADDITIONAL FIRE RELATED INFORMATION, SEE NFPA 30 OR NORTH AMERICAN EMERGENCY RESPONSE GUIDE 115.
CLASS B FIRE EXTINGUISHING MEDIA SUCH AS CO2, DRY CHEMICAL OR WATER SPRAY CAN BE USED. FIRE FIGHTING SHOULD BE ATTEMPTED ONLY BY THOSE WHO ARE ADEQUATELY TRAINED AND EQUIPPED WITH PROPER PROTECTIVE EQUIPMENT.
AVOID USING STRAIGHT WATER STREAMS. WATER SPRAY AND FOAM (AFFF/ATC) MUST BE APPLIED CAREFULLY TO AVOID FROTHING. AVOID EXCESSIVE APPLICATION. WATER CAN BE USED TO COOL EXPOSED SURFACES FROM AS FAR A DISTANCE AS POSSIBLE. KEEP RUN-OFF WATER OUT OF SEWERS AND WATER SOURCES.
ISOLATE AND EVACUATE AREA. SHUT OFF SOURCE IF SAFE TO DO SO. ADVISE NATIONAL RESPONSE CENTER (800-424-8802) IF SUBSTANCE HAS ENTERED A WATERWAY. NOTIFY LOCAL HEALTH AND POLLUTION CONTROL AGENCIES, IF APPROPRIATE. CONTAIN LIQUID WITH SAND OR SOIL. RECOVER AND RETURN FREE LIQUID TO PROPER CONTAINERS. USE SUITABLE ABSORBENT MATERIALS SUCH AS VERMICULITE, SAND, OR CLAY TO CLEAN UP RESIDUAL LIQUIDS.
COMPLY WITH ALL APPLICABLE OSHA, NFPA AND CONSISTENT LOCAL REQUIREMENTS. USE APPROPRIATE GROUNDING AND BONDING PRACTICES. STORE IN PROPERLY CLOSED CONTAINERS THAT ARE APPROPRIATELY LABELED AND IN A COOL, WELL-VENTILATED AREA. DO NOT EXPOSE TO HEAT, OPEN FLAME, OXIDIZERS OR OTHER SOURCES OF IGNITION. DO NOT CUT, DRILL, GRIND OR WELD ON EMPTY CONTAINERS SINCE THEY MAY CONTAIN EXPLOSIVE RESIDUES. HARMFUL CONCENTRATIONS OF HYDROGEN SULFIDE (H2S) GAS CAN ACCUMULATE IN EXCAVATIONS AND LOW-LYING AREAS AS WELL AS THE VAPOR SPACE OF STORAGE AND BULK TRANSPORT COMPARTMENTS. STAY UPWIND AND VENT OPEN HATCHES BEFORE UNLOADING. AVOID SKIN CONTACT. EXERCISE GOOD PERSONAL HYGIENE INCLUDING REMOVAL OF SOILED CLOTHING AND PROMPT WASHING WITH SOAP AND WATER.
LOCAL OR GENERAL EXHAUST REQUIRED IN ENCLOSED AREAS OR WITH INADEQUATE VENTILATION.
NOT NORMALLY REQUIRED FOR ROUTINE OPERATIONS. SUPPLIED AIR RESPIRATORS SHOULD BE USED IF OPERATING CONDITIONS CREATE AIRBORNE CONCENTRATIONS WHICH EXCEED EXPOSURE LIMITS FOR ANY INDIVIDUAL COMPONENTS (INCLUDING H2S). OBSERVE RESPIRATOR PROTECTION FACTOR CRITERIA CITED IN ANSI Z88.2. SELF- CONTAINED BREATHING APPARATUS SHOULD BE USED FOR FIRE FIGHTING.
NEOPRENE OR NITRILE GLOVES TO PREVENT SKIN CONTACT.
NO SPECIAL EYE PROTECTION IS NORMALLY REQUIRED. WHERE SPLASHING IS POSSIBLE, WEAR SAFETY GLASSES WITH SIDE SHIELDS.
USE EXPLOSION-PROOF EQUIMENT.
BOILING POINT: 100-1000 F MELTING POINT: NO DATA AVAILABLE SPECIFIC GRAVITY (H20=1): 0.8-1.0 PACKING DENSITY (KG/M3): NO DATA AVAILABLE % SOLUBILITY IN WATER: NEGLIGIBLE VAPOR DENSITY (AIR=1): NO DATA AVAILABLE VAPOR PRESSURE: 0-724 MMHG PH INFORMATION: NO DATA AVAILABLE % VOLATILES BY VOL: NO DATA AVAILABLE EVAPORATION RATE: NO DATA AVAILABLE APPEARANCE: AMBER TO BLACK VISCOUS LIQUID ODOR: MILD OR ROTTEN EGG ODOR ODOR THRESHOLD (PPM): NO DATA AVAILABLE
DENSITY: 6.6-8.2 LBS/GALLON
THE MATERIAL IS STABLE AT 70 F, 760MM PRESSURE.
EXCESSIVE HEAT, SOURCES OF IGNITION.
CARBON MONOXIDE, HYDROGEN SULFIDE, ALDEHYDES, AROMATIC, OTHER HYDROCARBONS.
STRONG OXIDIZING AGENTS SUCH AS CHLORATES, NITRATES, PEROXIDES.
WILL NOT OCCUR.
NO DATA AVAILABLE.
NO DATA AVAILABLE.
LIFETIME SKIN PAINTING STUDIES IN ANIMALS WITH CRUDE OIL FRACTIONS HAVE PRODUCED WEAK TO MODERATE CARCINOGENIC ACTIVITY FOLLOWING PROLONGED AND REPEATED EXPOSURE. WASHING THE ANIMALS' SKIN WITH SOAP AND WATER BETWEEN APPLICATIONS GREATLY REDUCES TUMOR FORMATION. REPEATED DERMAL APPLICATION OF TWO DIFFERENT CRUDE OILS IN RATS PRODUCED SYSTEMIC TOXICITY IN BLOOD, LIVER, THYMUS AND BONE MARROW. REPEATED DERMAL APPLICATION TO PREGNANT RATS PRODUCED MATERNAL TOXICITY AND FETAL DEVELOPMENTAL TOXICITY. HYDROGEN SULFIDE CONCENTRATIONS WILL VARY SIGNIFICANTLY DEPENDING ON THE SOURCE AND SULFUR CONTENT OF THE CRUDE. SWEET CRUDES (<0.5% SULFUR) MAY CONTAIN TOXICOLOGICALLY SIGNIFICANT LEVELS OF HYDROGEN SULFIDE IN THE VAPOR SPACES OF BULK STORAGE TANKS AND TRANSPORT COMPARTMENTS. CONCENTRATIONS OF H2S AS LOW AS 10 PPM OVER AN 8 HOUR WORKSHIFT MAY CAUSE EYE OR THROAT IRRITATION. PROLONGED BREATHING OF 50-100 PPM H2S VAPORS CAN PRODUCE SIGNIFICANT EYE AND RESPIRATORY IRRITATION. SOUR CRUDES COMMONLY CONTAIN EXTREMELY HIGH CONCENTRATIONS OF H2S (500-70,000 PPM) IN THE VAPOR SPACES OF BULK STORAGE VESSELS. EXPOSURE TO 250-600 PPM FOR 15-30 MINUTES CAN PRODUCE HEADACHE, DIZZINESS, NERVOUSNESS, STAGGERING GAIT, NAUSEA AND PULMONARY EDEMA OR BRONCHIAL PNEUMONIA. CONCENTRATIONS >1,000 PPM WILL CAUSE IMEMDIATE UNCONSCIOUSNESS AND DEATH THROUGH RESPIRATORY PARALYSIS. SUMMARY OF HEALTH EFFECT DATA ON CRUDE OIL COMPONENTS: THIS PRODUCT MAY CONTAIN BENZENE AT A LEVEL OF >0.1%. REPEATED OR PROLONGED EXPOSURE TO BENZENE AT CONCENTRATIONS IN EXCESS OF THE TLV MAY CAUSE SERIOUS INJURY TO BLOOD-FORMING ORGANS. SIGNIFICANT CHRONIC EXPOSURE TO BENZENE VAPOR HAS BEEN REPORTED TO PRODUCE VARIOUS BLOOD DISORDERS, RANGING FROM ANEMIA TO CANCER (DIFFERENT FORMS OF LEUKEMIA) IN MAN. BENZENE PRODUCED TUMORS IN RATS AND MICE IN LIFETIME CHRONIC TOXICITY STUDIES, BUT THE RESPONSE HAS NOT BEEN CONSISTENT ACROSS SPECIES, STRAIN, SEX OR ROUTE OF EXPOSURE. ANIMAL STUDIES ON BENZENE HAVE DEMONSTRATED IMMUNE TOXICITY, CHROMOSOMAL ABERRATIONS, TESTICULAR EFFECTS AND ALTERATIONS IN REPRODUCTIVE CYCLES AND EMBRYO/FETOTOXICITY, BUT NOT TERATOGENICITY. THIS PRODUCT MAY CONTAIN HEXANE AT A LEVEL OF >1.0%. STUDIES IN LABORATORY ANIMALS HAVE PRODUCED SYSTEMIC TOXICITY IN BLOOD, SPLEEN AND LUNGS. FETOTOXICITY HAS BEEN OBSERVED AT HEXANE CONCENTRATIONS THAT PRODUCED MATERNAL TOXICITY. LONG TERM EXPOSURE TO HIGH CONCENTRATIONS OF HEXANE HAS BEEN SHOWN TO CAUSE TESTICULAR EFFECTS AND NERVOUS SYSTEM DAMAGE. THIS PRODUCT MAY CONTAIN TOLUENE AT A LEVEL OF >1.0%. DELIBERATE INHALATION OF HIGH CONCENTRATIONS OF TOLUENE HAS BEEN SHOWN TO CAUSE LIVER, KIDNEY AND BRAIN DAMAGE AND CENTRAL NERVOUS SYSTEM EFFECTS. EXCESSIVE TOLUENE EXPOSURE MAY CAUSE CARDIAC SENSITIZATION AND POSSIBLE HEARING LOSS. EXPOSURE TO PREGNANT RATS AND MICE DURING GESTATION TO TOLUENE PRODUCED SOME MATERNAL AND DEVELOPMENTAL TOXICITY. DECREASED LEARNING CAPABILITY AND DEFICITS IN OPERANT BEHAVIOR HAVE BEEN OBSERVED IN ANIMALS EXPOSED TO TOLUENE ABOVE THE TLV. THIS PRODUCT MAY CONTAIN XYLENE AT A LEVEL OF >1.0%. GROSS OVEREXPOSURE IN HUMANS TO XYLENES HAS BEEN REPORTED TO CAUSE LUNG, LIVER, KIDNEY, HEART AND BRAIN DAMAGE AS WELL AS NEUROLOGIC DISTURBANCES. EXCESSIVE XYLENE EXPOSURE MAY CAUSE CARDIAC SENSITIZATION. LABORATORY ANIMALS EXPOSED TO HIGH DOSES OF XYLENE SHOWED EVIDENCE OF HEARING LOSS AND EFFECTS IN LIVER, KIDNEYS, LUNGS, SPLEEN, HEART AND ADRENALS. EXPOSURE TO PREGNANT ANIMALS DURING GESTATION TO SIGNIFICANT CONCENTRATIONS OF XYLENE PRODUCED MATERNAL, FETAL AND DEVELOPMENTAL TOXICITY. REPEATED INHALATION OF HIGH XYLENE CONCENTRATIONS HAVE SHOWN BEHAVIORAL CHANGES IN ANIMALS AND MAN. COMPONENTS OF CRUDE OIL DO NOT PRESENT A SIGNIFICANT HEALTH RISK IN THE CONCENTRATIONS PRESENT IN CRUDE OIL AT EXPOSURES NOT EXCEEDING THE EXPOSURE LIMITS STATED IN SECTION 2.
COATING ACTION OF OIL CAN DESTROY BIRDS, PLANKTON, ALGAE AND FISHES. KEEP OUT OF ALL BODIES OF WATER AND SEWAGE DRAINAGE SYSTEMS.
THIS PRODUCT AS SUPPLIED IS NOT SPECIFICALLY LISTED AS AN EPA RCRA HAZARDOUS WASTE ACCORDING TO FEDERAL REGULATIONS (40 CFR 261-271). HOWEVER, WHEN DISCARDED OR DISPOSED OF, IT MAY MEET THE CRITERIA OF AN "IGNITABLE" HAZARDOUS WASTE. THIS PRODUCT COULD ALSO CONTAIN BENZENE AT >0.5 PPM AND COULD EXHIBIT THE CHARACTERISTICS OF "TOXICITY" AS DETERMINED BY THE TOXICITY CHARACTERISTIC LEACHING PROCEDURE (TCLP). THIS MATERIAL COULD ALSO BECOME A HAZARDOUS WASTE IF MIXED OR CONTAMINATED WITH A LISTED HAZARDOUS WASTE. IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF DISPOSAL MATERIAL IS HAZARDOUS ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS.
49 CFR 172.101:
PROPER SHIPPING NAME: PETROLEUM CRUDE OIL
DOT CLASSIFICATION: 3
DOT IDENTIFICATION NUMBER: UN 1267
PACKING GROUP: PG II
THE FOLLOWING REGULATIONS APPLY TO THIS PRODUCT:
OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200):
THIS PRODUCT HAS BEEN EVALUATED AND DETERMINED TO BE HAZARDOUS AS
DEFINED IN OSHA'S HAZARD COMMUNICATION STANDARD.
EPA TOXIC SUBSTANCES CONTROL ACT (40 CFR PART 710):
THIS PRODUCT AND/OR ITS COMPONENTS ARE LISTED ON THE TSCA CHEMICAL
INVENTORY.
EPA SARA TITLE III SUPERFUND AMENDMENTS & REAUTHORIZATION ACT - EMERGENCY
PLANNING & COMMUNITY RIGHT-TO-KNOW ACT OF 1986.
EXTREMELY HAZARDOUS SUBSTANCES (40 CFR PART 355):
THIS PRODUCT CONTAINS THE FOLLOWING COMPONENT(S) IDENTIFIED ON APPENDIX
A AND B OF THE EXTREMELY HAZARDOUS SUBSTANCE LIST (AT A LEVEL OF 1% OR
GREATER IF HAZARDOUS; 0.1% OR GREATER IF CARCINOGENIC):
REPORTABLE THRESHOLD PLANNING
---COMPONENT--- ---QUANTITY (LBS)--- ---QUANTITY (LBS)---
HYDROGEN SULFIDE 100 500
EMERGENCY RELEASE NOTIFICATIONS (40 CFR PART 355):
THIS PRODUCT CONTAINS THE FOLLOWING COMPONENT(S) IDENTIFIED EITHER AS AN
EXTREMELY HAZARDOUS SUBSTANCE (40 CFR 355) OR A CERCLA HAZARDOUS
SUBSTANCE (40 CFR 302) WHICH IN CASE OF A SPILL OR RELEASE MAY BE
SUBJECT TO EMERGENCY RELEASE REPORTING REQUIREMENTS:
HYDROGEN SULFIDE (REPORTING QUANTITY = 100 LBS)
MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR PART 370):
THE FOLLOWING EPA HAZARD CATEGORIES APPLY TO THIS PRODUCT:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
FIRE HAZARD
MSDS'S OR A LIST OF MSDS'S AND THEIR HAZARDS (SEE EPA HAZARD CATEGORIES
ABOVE) MAY BE REQUIRED TO BE SUBMITTED TO THE STATE EMERGENCY RESPONSE
COMMISSION (SERC), LOCAL EMERGENCY PLANNING COMMITTEE (LEPC) AND LOCAL
FIRE DEPARTMENT (LFD.
IN ADDITION, A TIER II OR TIER I FORM MAY BE REQUIRED TO BE SUBMITTED
ANNUALLY TO THE SERC, LEPC AND LFD IF APPLICABLE THRESHOLD REPORTING
QUANTITIES ARE EXCEEDED. CURRENT FEDERAL THRESHOLDS ARE:
10,000 POUNDS OR MORE OF AN OSHA HAZARDOUS SUBSTANCE
OR
500 POUNDS OR THE THRESHOLD PLANNING QUANTITY, WHICHEVER IS
LESS, OF AN EXTREMELY HAZARDOUS SUBSTANCE.
NOTE: THRESHOLDS MAY VARY ACCORDING TO LOCAL AND STATE REGULATIONS.
TOXIC CHEMICAL RELEASE REPORTING (40 CFR PART 372):
THIS PRODUCT CONTAINS THE FOLLOWING COMPONENT(S) (AT A LEVEL OF 1% OR
GREATER IF HAZARDOUS; 0.1% OR GREATER IF CARCINOGENIC) THAT MAY BE
SUBJECT TO REPORTING ON THE TOXIC RELEASE INVENTORY (TRI) FORM R:
---COMPONENT--- ---CAS NUMBER---
BENZENE 71-43-2
TOLUENE 108-88-3
XYLENE 1330-20-7
HEXANE 110-54-3
STATE AND COMMUNITY RIGHT-TO-KNOW REGULATIONS:
THIS MATERIAL MAY BE REGULATED BY LOUISIANA'S RIGHT-TO-KNOW LAW
(REGULATORY STATUTE 30:2361).
NFPA CLASSIFICATION HMIS CLASSIFICATION HAZARD RATING
HEALTH: 1 HEALTH: 1 0 - LEAST
FIRE: 3 FIRE: 3 1 - SLIGHT
REACTIVITY: 0 REACTIVITY: 0 2 - MODERATE
OTHER: - PERSONAL PROTECTION: * 3 - HIGH
4 - EXTREME
* SEE SECTION 8 FOR GUIDANCE IN SELECTION OF PERSONAL PROTECTIVE
EQUIPMENT.
Updated: